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TIG4: `[#7X2:1]@[#6X3:2]~[#6X3:3]@[*:4]`

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TIG5a: `[#7X3,#8X2,#16X2:1]~[#6X3:2]~[#6X3:3](=[#8X1])~[*:4]`

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TIG5b: `[#7X3,#8X2,#16X2:1]@[#6X3:2]~[#6X3:3]@[*:4]`

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