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Parameter

Initial values taken

Linear + cyclo alkanes

Cyclo alkanes only

Linear alkanes only

Std. dev. of the three

1.3.0 for reference

b1, length, [#6X4:1]-[#6X4:2]

1.00

1.50

1.50

1.46

0.02

1.52

b1, k, [#6X4:1]-[#6X4:2]

500.00

488.76

487.34

488.01

0.58

517.22

b83, length, [#6X4:1]-[#1:2]

1.00

1.09

1.09

1.09

0.00

1.09

b83, k, [#6X4:1]-[#1:2]

700.00

699.88

699.88

699.86

0.01

754.07

a2, angle, [#1:1]-[#6X4:2]-[#1:3]

90.00

110.51

110.46

110.09

0.19

114.29

a2, k, [#1:1]-[#6X4:2]-[#1:3]

60.00

89.77

90.36

82.16

3.74

66.55

*length in angstroms, angle in degrees, k in kcal/mol/ang^2 or kcal/mol/rad^2

Test fits with sulfonamide

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