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Here are the plots for fit7 for the TIG parameters, k1_bondorder1 and k1_bondorder2 for each parameter

TIG0:

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TIG1c

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TIG1d

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TIG2

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TIG3

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TIG4

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TIG5a

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TIG5b

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TIG6

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TIG7

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TIG8

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TIG5a, TIG6, TIG7, TIG8 have gradients that vary on a large scale here.